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Besirc IRC (freeware) - Win
Bersirc is an open source IRC client that runs on Windows (Linux and Mac OS X ports under development) by utilizing the Claro GUI Toolkit.
http://bersirc.free2code.net/index.php/home

Broadcaster (freeware) - Win
Broadcaster's StudioPRO allows you to capture any video playing on your screen including live streaming video and pre-recorded video clips playing on any media player.
http://www.broadcaster.com/tools/?p=studiopro

Gaim (open source) - Win/Mac/Linux
Gaim is a multi-protocol instant messaging (IM) client for Linux, BSD, MacOS X, and Windows. It is compatible with AIM and ICQ (Oscar protocol), MSN Messenger, Yahoo!, etc.
http://gaim.sourceforge.net/

Gizmo (freeware) - Win/Mac/Linux
An internet telephone that is simple as instant messaging. Works on a variety of platforms.
http://www.gizmoproject.com/index.html

goowy (service)
goowy is an integrated set of intuitive tools that help you communicate and share on the web.
http://www.goowy.com/

Meebo (service)
Access you Instant Messaging Services through the browser. Can link to AIM, Yahoo, GoogleTalk and MSN.
http://www.meebo.com

Plugoo (service)
Plugoo enables you to chat directly from your Instant Messenger with any visitor of your blog, personal webpage or e-sales site.
http://www.plugoo.com/

Sightspeed (service) - Win/Mac
[$4.95 month, $49.95 year] SightSpeed turns your PC or Mac into an high-quality, easy-to-use Video Phone.
http://www.sightspeed.com/

Skype (freeware) - Win/Mac/Linux
Skype is a little program for making free calls over the internet to anyone else who also has Skype.
http://www.skype.com/